Crystal structure,physical properties and bond valence analysis of NaLuP2O7

Single crystals of a diphosphate NaLuP₂O₇ have been synthesized by the flux method and characterized by single-crystal X-Ray diffraction. NaLuP₂O₇ crystallizes in the monoclinic system with P2₁/n space group with cell parameters: a = 8.9985(8) Å, b = 5.3473(5) Å, c = 12.756(1) Å, β = 103.174° (1), V = 597.67 (9) Å³, Z = 4. Its structure consists of a three-dimensional framework of P₂O₇ units that are corner-shared by LuO₆ octahedra, forming tunnels running parallel to [010] which are occupied by Na atoms. NaLuP₂O₇ powder was characterized by XRD, SEM, FTIR and Raman spectroscopy. The activation energy of (1.49 eV) obtained by electrical measurements suggests the charge carriers to be the sodium cations. The activation energies obtained from impedance and loss spectra were analyzed in order to explain the mechanism of conduction. The correlation between ionic conductivity of NaLuP₂O₇ and its crystallographic structure was investigated and the most probable transport pathway model was determined.     

Prediction of hydrodynamic performance of an FLNG system in side-by-side offloading operation

Floating liquefied natural gas (FLNG) is a type of liquefied natural gas (LNG) production system that shows prospects in exploitation of stranded offshore gas fields. The dynamic performance of an FLNG system in side-by-side configuration with a LNG carrier under the combined actions of wave, current and wind can be quite complex. This paper presents a comprehensive study on the hydrodynamics of an FLNG system with a focus on the nonlinear coupling effects of vessels and connection systems based on the concept FLNG prototype recently designed for South China Sea. In this study, the hydrodynamic characteristics of the two floating vessels connected through hawsers and fenders are investigated using a state-of-the-art time-domain simulation code SIMO, considering their mechanical and hydrodynamic coupling effects. The simulation model consisting of FLNG and LNG carrier is developed and calibrated by a series of model tests including a tuned damping and viscous levels. The hydrodynamic performances of the two floating vessels under an extreme sea state during side-by-side offloading operation are obtained, and their relative motions and the force responses of the connection hawsers and fenders are analyzed. Sensitivity studies are conducted to clarify contributions from the pretension and the stiffness of the connection hawsers. The effects on the hydrodynamic performance of the vessels and on the loads of the connection system are also investigated.     

A postscript on aggregate Farrell efficiencies

In this note we derive alternative weighting schemes that complement those of Färe and Zelenyuk (2003) for consistent aggregation of Farrell efficiencies when the technology exhibits (global) constant returns to scale.     

Symmetry and stability of asymptotic profiles for fast diffusion equations in annuli

This paper is concerned with stability analysis of asymptotic profiles for (possibly sign-changing) solutions vanishing in finite time of the Cauchy–Dirichlet problems for fast diffusion equations in annuli. It is proved that the unique positive radial profile is not asymptotically stable, and moreover, it is unstable for the two-dimensional annulus. Furthermore, the method of stability analysis presented here will be also applied to exhibit symmetry breaking of least energy solutions.     

A new color image cryptosystem via hyperchaos synchronization

This paper proposes a novel color image cryptosystem based on synchronization of two different six-dimensional hyperchaotic systems. In the transmitter end, we apply the drive system to generate the diffusion matrices and scrambling ones, which are used to change the image pixel value and position, respectively. Thus the ciphered image is obtained. In the receiver, synchronization of two nonidentical hyperchaotic systems can be achieved by designing the appropriate controllers. The response system is employed to yield the corresponding diffusion matrices and scrambling ones using the same generation method in the encryption algorithm. Then the cipher-image can be decrypted by the decryption algorithm, which is similar to that of the encryption process but in the reversed order. The experimental results show that the presented image cryptosystem has high security and can resist noise and crop attacks.     

A new distance measure including the weak preference relation: Application to the multiple criteria aggregation procedure for mixed evaluations

We introduce a new distance measure between two preorders that captures indifference, strict preference, weak preference and incomparability relations. This measure is the first to capture weak preference relations. We illustrate how this distance measure affords decision makers greater modeling power to capture their preferences, or uncertainty and ambiguity around them, by using our proposed distance measure in a multiple criteria aggregation procedure for mixed evaluations.     

How does the ambiguity of the electronic stress tensor influence its ability to serve as bonding indicator

The electronic stress tensor is not uniquely defined. Possible bonding indicators originating from the quantum stress tensor may inherit this ambiguity. Based on a general formula of the stress tensor this ambiguity can be described by an external parameter λ for indicators derived from the scaled trace of the stress tensor (whereby the scaling function is proportional to the Thomas–Fermi kinetic energy density). The influence of λ is analyzed and the consequences for the representation of chemical bonding are discussed in detail. It is found that the scaled trace of the stress tensor may serve as suitable bonding indicator over a wide range of λ values, excluding the value range between ?0.15 and ?0.48. Focusing on the eigenvalues of the stress tensor, it is found that the sign of the eigenvalues heavily depends on the chosen representation of the stress tensor. Therefore, chemical bonding analyses which are based on the interpretation of the eigenvalue sign (e.g., the spindle structure) are strongly dependent on the chosen form of the stress tensor. © 2014 Wiley Periodicals, Inc.     

基于S变换的地震信号降噪方法研究

S变换在分析非平稳信号时能有效地反映出频率随时间的变化,但由于其窗函数是固定不变的,在实际中应用受到了限制.从基本理论出发,推导出一种改进的S变换形式,并对合成信号分别进行傅立叶变换、s变换和改进的S变换,通过对比发现:改进的s变换方法能够更好地分辨非平稳信号的频率特性,比S变换具有更高的分辨率.最后应用改进的s变换方法对地震背景噪声数据进行了去噪处理,取得了较好的结果.     

连续流动分析法测定水中的阴离子表面活性剂

在GB/T 7494–1987法的基础上将自动进样、在线萃取、在线分离技术与分光光度法相结合,测定水中阴离子表面活性剂的含量。在分析过程中利用二次萃取和分离有效除去干扰物质,提高了分析的准确度和灵敏度。标准工作曲线线性相关系数为0.999 2,检出限为0.007 mg/L,测定结果的相对标准偏差为2.0%~2.4%(n=6),加标回收率为95.0%~98.0%。连续流动注射分析法操作简单,基线稳定速度快,连续分析效果好,大大降低了氯仿对人体的危害,适合大批量水质中阴离子表面活性剂含量的分析。